Synthesis and application of non- bioaccumulable fluorinated surfactants: a review
作者机构：Key Laboratory of Leather Chemistry and Engineering of Ministry of EducationSichuan UniversityChengdu 610065China National Engineering Laboratory for Clean Technology of Leather ManufactureSichuan UniversityChengdu 610065China
出 版 物：《Journal of Leather Science and Engineering》 (皮革科学与工程（英文）)
年 卷 期：2021年第3卷第1期
页 面：67-81页
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学]
基 金：National Natural Science Foundation of China(No.22078207) Sichuan Science and Technology Program(No.2020YFG0069) Fundamental Research Funds for the Central Universities(China)
主 题：Non-bioaccumulable fluorinated surfactants Synthesis Structure-activity relationship Application
摘 要：Due to negative effects of conventional fluorinated surfactants with long perfluorocarbon chain(C_(x)F_(2x+1),x≥7)like perfluorooctanoic acid(PFOA)and perfluorooctane sulfonate(PFOS),these conventional long perfluorocarbon chain surfactants have been restricted in many industrial ***,their potential non-bioaccumulable alternatives have been developed to meet the requirements of environmental sustainable *** this paper,the recent advances of potential non-bioaccumulable fluorinated surfactants with different fluorocarbon chain structures,including the short perfluorocarbon chain,the branched fluorocarbon chain,and the fluorocarbon chain with weak points,are reviewed from the aspects of synthesis processes,properties,and structure-activity *** their applications in emulsion polymerization of fluorinated olefins,handling membrane proteins,and leather manufacture also are ***,the challenges embedded in the current non-bioaccumulable fluorinated surfactants are also highlighted and discussed with the hope to provide a valuable reference for the prosperous development of fluorinated surfactants.
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