A nickel/organoboron catalyzed metallaphotoredox platform for C(sp^(2))-P and C(sp^(2))-S bond construction

作     者：Yuan Zhu Weisai Zu Qing Tian Zifeng Cao Yu Wei Liang Xu 

作者机构：School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang BingtuanShihezi UniversityShihezi832003China 

出 版 物：《Organic Chemistry Frontiers》 (有机化学前沿（英文）)

年 卷 期：2022年第9卷第4期

页      面：1070-1076页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We acknowledge the financial support by the National Natural Science Foundation of China(No.21963010) Shihezi University(funding to L.X.,CXRC201602) 

主　　题：boron nickel catalyzed 

摘      要：Herein,an organoboron photocatalyst,aminoquinolate diarylboron(AQDAB),is utilized collaboratively with a nickel catalyst in metallaphotoredox catalyzed C(sp^(2))–P and C(sp^(2))–S cross-coupling *** strategy effectively couples aryl halides with diarylphosphine oxides and thiols at room temperature under an air atmosphere,affording the corresponding triarylphosphine oxides and thioethers in generally moderate to good yields.