Synthesis, Crystal Structure and Electrochemical Properties of 2-Chlorobenzaldehyde Thiosemicarbazone

作     者：Sheng Yi ZHANG Yu Peng TIAN(Department of chemistry, Anhui University, Hefei, 230039)(Coordination Chemistry Institute State Key Laboratory of Naning University. Nanjing. 210093) 

作者机构：Department of Chemistry Anhui University Hefei 230039 China Coordination Chemistry Institute State Key Laboratory Nanjing University Nanjing 210093 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1997年第8卷第5期

页      面：459-460页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Crystal Structure and Electrochemical Properties of 2-Chlorobenzaldehyde Thiosemicarbazone Synthesis 

摘      要：The title compound crystallized in space goups P2(1)/c with Z=4, in a unit cell of dimensions, a=12.964(4), b=5.131(5), c=14.970(1)Angstrom; V=9331(1) Angstrom(3) Dc=1.429gcm(-3), mu=0.541mm(-1), R=0.045, Rw=0.059. The equilibrium constant of the ligand with CdBr2 was obtained by polarographic method. Crystal structure determination revealed that the molecule is in transconformation and non-hydrogen atoms of the molecule are in one plane except N(3) atom.