Electrochemically-mediated C-H functionalization of allenes and 1,3-dicarbonyl compounds to construct tetrasubstituted furans

作     者：Mu-Xue He Yan Yao Chun-Zhi Ai Zu-Yu Mo Yu-Zheng Wu Qi Zhou Ying-Ming Pan Hao-Tao Tang 

作者机构：State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesSchool of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilin 541004China School of Public HealthGuilin Medical UniversityGuilin 541004China Pharmacy SchoolGuilin Medical UniversityGuilin 541004China Adesis Inc.A Universal Display companyNew CastleDelaware 19720USA 

出 版 物：《Organic Chemistry Frontiers》 (有机化学前沿（英文）)

年 卷 期：2022年第9卷第3期

页      面：781-787页

核心收录：

学科分类：07[理学] 0806[工学-冶金工程] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was supported by National Natural Science Foundation of China(22161008,21861006,22061003) Guangxi Natural Science Foundation of China(2021GXNSFFA220005) the Chunhui Program(GX2019001). 

主　　题：compounds substituted furan 

摘      要：C-H functionalization of allenes is an available strategy to construct heterocyclic compounds.Herein we propose a sus-tainable electrocatalytic C-H activation for the synthesis of novel highly functionalized tetrasubstituted furans,which is accomplished by intermolecular cyclization of allenes and 1,3-dicarbonyl compounds.