Thermophysical properties of pure gases and mixtures at temperatures of 300-30000K and atmospheric pressure:thermodynamic properties and solution of equilibrium compositions

作     者：Zhongyuan CHI Weijun ZHANG Qiangda YANG 池中源;张卫军;杨强大

作者机构：School of MetallurgyNortheastern UniversityShenyang 110819People's Republic of China 

出 版 物：《Plasma Science and Technology》 (等离子体科学和技术（英文版）)

年 卷 期：2021年第23卷第12期

页      面：161-175页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Key Research and Development Program of China(No.2017YFA0700300) the Fundamental Research Funds for the Central Universities(No.N2025032) the Liaoning Provincial Natural Science Foundation(No.2020-MS-362) 

主　　题：plasma equilibrium compositions thermodynamic properties homotopy Levenberg-Marquardt algorithm(HLMA) auxiliary equations 

摘      要：The equilibrium compositions and thermodynamic properties(density,enthalpy,etc at constant pressure)of plasma of pure gases and mixtures under local thermodynamic nonequilibrium have been calculated in this *** homotopy Levenberg-Marquardt algorithm was proposed to accurately solve nonlinear equations with singular Jacobian matrices,and is constructed by the Saha equation and Guldberg-Waage equation combined with mass conservation,the electric neutrality principle and Dalton’s partial pressure law,to solve the problem of dependence on the initial value in the process of iteration *** this research,the equations at a higher temperature were solved and used as the auxiliary equations,and the homotopy control parameters’sequence of the homotopy equations was selected by equal *** auxiliary equations,the iterative initial value was obtained by assuming that there were only the highestvalence atomic cations and electrons at this temperature,and the plasma equilibrium composition distribution with the required accuracy was ultimately solved under the current conditions employing the Levenberg-Marquardt *** control parameter sequence was arranged according to the geometric sequence and the homotopy step was gradually shortened to ensure continuity of the homotopy ***,the equilibrium composition and thermodynamic properties of pure N_(2),Mg(30%)-CO_(2)(70%)and Mg(40%)-CO(50%)-N_(2)(10%)mixture plasma at atmospheric pressure were calculated and the calculation process of some specified temperatures was shown and *** calculation accuracy of equilibrium composition is higher than other findings in the *** results for the thermodynamic properties are in good agreement with data reported by the literature.