Synthesis of 2-trifluoromethylquinolines through rhodium-catalysed redox-neutral[3+3]annulation between anilines and CF_(3)-ynones using traceless directing groups

作     者：Haichao Huang Hailong Wang Chao Gong Zhenjing Zhuang Wenmin Feng Si-Hai Wu Lianhui Wang 

作者机构：School of MedicineHuaqiao UniversityQuanzhou362021P.R.China 

出 版 物：《Organic Chemistry Frontiers》 (有机化学前沿（英文）)

年 卷 期：2022年第9卷第2期

页      面：413-419页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by NSF of China(no.21602064 and 22004041) the Science and Technology Project of Quanzhou City(2018C073R) the Instrumental Analysis Center of Huaqiao University 

主　　题：properties. aniline neutral 

摘      要：Rhodium-catalysed regioselective redox-neutral[3+3]-cycloaddition of anilines with CF_(3)-ynones was achieved via a traceless directing group strategy.A variety of substituted 2-trifluromethylquinoline compounds were obtained in good to excellent yields,which exhibited favorable blue emission properties.