Halogenated benzothiadiazole-based conjugated polymers as efficient photocatalysts for dye degradation and oxidative coupling of benzylamines

作     者：Chu Chu Yuancheng Qin Cailing Ni Jianping Zou Chu Chu;Yuancheng Qin;Cailing Ni;Jianping Zou

作者机构：Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources RecycleNanchang Hangkong UniversityNanchang 330063China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2022年第33卷第5期

页      面：2736-2740页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：financially supported by National Natural Science Foundation of China(No.52173099) the Science and Technology Department of Jiangxi Province(No.20192BBEL50025) Nanchang Hangkong University(No.EA201902288) the Special Fund for Graduate Innovation(No.YC2020-011) 

主　　题：Conjugated polymer Band gap Dye degradation Photocatalysis Benzylamine oxidation 

摘      要：Donor-acceptor(D-A)conjugated polymers are widely used in photovoltaic applications and heteroge-neous catalysis due to their tunable building block and pre-designable ***,a series of ad-justable Donor-acceptor(D-A)benzothiodiazole-based conjugated polymers were designed and *** photocatalytic performance could be improved by fine-tuning the chemical structure by halo-gen substitution(F or Cl).The polymers exhibited excellent optoelectronic properties and were effective photocatalysts for the degradation of RhB and MO dyes,as well as promoting the oxidative coupling of *** degradation of RhB and MO occurred in 30 min under visible light radiation,while the yield of benzylamine coupling mediated by superoxide anion was as high as 82%.Systematic characterization methods were used to gain insights on the unique photocatalytic performance of the *** findings provide further insights into the design and synthesis of benzothiadiazole-based conjugated polymers as promising organic photocatalysts for solar energy conversion.