Formation of silacycles via metal-mediated or catalyzed Si-C bond cleavage

作     者：WANG LiLi DUAN Zheng 

作者机构：College of Chemistry and Molecular EngineeringZhengzhou University 

出 版 物：《Chinese Science Bulletin》 (中国科学通报)

年 卷 期：2013年第58卷第3期

页      面：307-315页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Natural Science Foundation of China (21072179) 

主　　题：键断裂 介导 金属 材料科学 有机化学 衍生物 催化 合成 

摘      要：Silacycles play a very important role in modern organic chemistry and materials *** of silacyclic skeletons via metal-mediated or catalyzed Si-C bond cleavage has attracted much recent *** interesting and useful synthetic strategies have been reported in the *** this review,we have summarized recent developments on metal-mediated or catalyzed Si-C bond cleavage,which lead to the synthesis of silacycles,including silacyclobutenes,silacyclopentanes,silacyclopentadienes(siloles),6-membered silacycles,and their derivatives.