Determination of Thermal Properties of Cuts and Residue Streams Obtained in the Molecular Distillation Process
Determination of Thermal Properties of Cuts and Residue Streams Obtained in the Molecular Distillation Process作者机构:UNICAMP School of Chemical Engineering University of Campinas Campinas- SP 13083-970 Brazil CENPES/PDP/TPAP Oil-valuation proeesses Brazil
出 版 物:《Journal of Chemistry and Chemical Engineering》 (化学与化工(英文版))
年 卷 期:2011年第5卷第8期
页 面:684-690页
学科分类:081702[工学-化学工艺] 081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 081701[工学-化学工程]
主 题:Molecular distillation heavy oil heat transport specific heat enthalpy thermal conductivity differential scanning calorimetry.
摘 要:A real-time sensing of the molecular distillation process temperature by a FLUKE brand thermograph Ti50 IR FlexCam and thermography technique was realized. After completion of the molecular distillation, three properties of heat transport chain cuts and residues obtained in the process were estimated by Differential Scanning Calorimetry (DSC) (specific heat, enthalpy, thermal conductivity). These properties are of great importance for improving oil characterization and for future modeling and simulation of the molecular distillation process. The results show that through the method of Differential Scanning Calorimetry, profiles have been obtained from the variation of specific heat, enthalpy and thermal condutivity as a function of temperature for samples of cuts from the distillation (ASTM D-2892) and fractions of distillate and residue from the process of molecular distillation.