Ligand-Enabled NiH-Catalyzed Migratory Hydroamination:Chain Walking as a Strategy for Regiodivergent/Regioconvergent Remote sp^(3)C–H Amination

作     者：Yulong Zhang Jun He Peihong Song You Wang Shaolin Zhu 

作者机构：State Key Laboratory of Coordination ChemistryJiangsu Key Laboratory of Advanced Organic MaterialsChemistry and Biomedicine Innovation Center(ChemBIC)School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093 College of ChemistryChongqing Normal UniversityChongqing 401331 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2021年第3卷第9期

页      面：2259-2268页

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：by the National Natural Science Foundation of China(21702102 and 21772087),NSF of Jiangsu Province(BK20190281) the Six Kinds of Talent Project of Jiangsu Province(JNHB-003) the Program for High-Level Entrepreneurial and Innovative Talents Introduction of Jiangsu Province(Group Program) 

主　　题：C–H activation amination chain walking nickel regioselectivity 

摘      要：Direct and positionally selective aliphatic C–H functionalization is an attractive means with which to streamline chemical *** many possible reaction sites,most traditional methods need a polar-directing group nearby to achieve high regioand chemoselectivity and are often restricted to a single site of ***,we report a nondirected,remote sp^(3)C–H amination process with predictable and switchable regioselectivity.