Crystal structures and magnetic properties of cyano-bridged 4f-3d complexes

作     者：闫冰 陈志达 

作者机构：Beijing 100871 China College of Chemistry and Molecular Engineering Peking University Peking University-Hong Kong University Joint Laboratory of Rare Earth Materials and Bioinorganic Chemistry State Key Laboratory of Rare Earth Material Chemistry and Applications 

出 版 物：《Progress in Natural Science:Materials International》 (自然科学进展·国际材料(英文))

年 卷 期：2001年第11卷第6期

页      面：3-12页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Project supported by the National Natural Science Foundation of China (Grant No. 29831010  20023005)  the State Key Project of Fundamental Research of China (Grant No. 1998061306) and the China Postdoctoral Science Foundation 

主　　题：molecular-based magnets cyano-bridged complexes 4f-3d crystal structures magnetic properties. 

摘      要：The most recent research progress in the fields of the crystal structure and magnetochemistry for rare earth-transition metal cyano-bridged complexes is reviewed in detail. The emphasis is put on the introduction to the research achievements of our group in this field, including all the types of complexes with different crystal structures in these systems such as dinuclear, trinuclear, one-dimensional chain and hydrogen-bonded network ion-pairs. At the same time a few examples of rare earth-transition metal molecular-based magnets have been found to exhibit excellent magneto-chemical properties, such as the long-range magnetic ordering, the higher critical temperature Tc and the stronger coercive force. These results will be expected to promote the research development in this field.