A millimeter-sized negatively charged polymer embedded with molybdenum disulfide nanosheets for efficient removal of Pb(Ⅱ)from aqueous solution

作     者：Guangze Nie Shijun Qiu Xiang Wang Yan Du Qingrui Zhang Yang Zhang Hengle Zhang Guangze Nie;Shijun Qiu;Xiang Wang;Yan Du;Qingrui Zhang;Yang Zhang;Hengle Zhang

作者机构：School of Environmental Science and EngineeringNanjing Tech UniversityNanjing 211816China Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource ReuseYanshan UniversityQinhuangdao 066004China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2021年第32卷第7期

页      面：2342-2346页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the financial support from the National Key Research and Development Program of China(No.2017YFE0107200) Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX20_1105) NSFC(No.21876145) the Supporting Plan for 100 Excellent Innovative Talents in Colleges and Universities of Hebei Province(No.SLRC2019041) Open Foundation of State Key Laboratory of Pollution Control and Resource Reuse(No.PCRRF18026,Nanjing University)。 

主　　题：Molybdenum disulfide Polystyrene host Lead removal Nanocomposite Adsorption 

摘      要：Molybdenum disulfide(MoS_(2))has excellent trapping ability for lead ions whereas its micro-/nanoscale size has greatly impeded its practical applications in the flow-through systems.Herein,a millimetersized nanocomposite MoS_(2)-001 was synthesized for Pb^(2+)removal by loading MoS_(2) nanosheets into a polystyrene cation exchanger D-001 by a facile hydrothermal method.The proposed structure and adsorption mechanism of MoS_(2)-001 was confirmed by the scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),and X-ray photoelectron spectro scopy(XPS)analysis.The nanocomposite showed outstanding adsorption capacity and rapid adsorption kinetic for Pb^(2+)removal,and the adsorption behavior followed the Langmuir adsorption model and pseudo-firstmodel kinetic model.Pb^(2+)uptake by MoS_(2)-001 still maintains a high level even in the presence of extremely highly competitive ions(Ca(Ⅱ)and Mg(Ⅱ)),suggesting its high selectivity for Pb^(2+)adsorption.Besides,the fixed-bed column experiments further certified that MoS_(2)-001 is of great potential for Pb^(2+)removal from the wastewater in practical engineering applications.Even more gratifying is that the exhausted MoS_(2)-001 can be regenerated by NaCl-EDTANa_(2) solution without any significant adsorption capacity loss.Consequently,all the results indicated that MoS_(2)-001 is a promising candidate adsorbent for lead-containing wastewater treatment.