Preparation of bio-oil by catalytic pyrolysis of corn stalks using red mud
作者机构:School of Agricultural Engineering and Food ScienceShandong University of TechnologyZibo 255091China Shandong Research Center of Engineering and Technology for Clean EnergyZibo 255091China
出 版 物:《International Journal of Agricultural and Biological Engineering》 (国际农业与生物工程学报(英文))
年 卷 期:2016年第9卷第5期
页 面:177-183页
核心收录:
学科分类:0710[理学-生物学] 0810[工学-信息与通信工程] 07[理学] 070304[理学-物理化学(含∶化学物理)] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0812[工学-计算机科学与技术(可授工学、理学学位)]
基 金:the National Natural Science Foundation of China(No.51276103) the National Natural Science Foundation of China(No.51406109)。
主 题:red mud catalytic pyrolysis corn stalk powder bio-oil
摘 要:Red mud is a solid waste residue with alkaline nature(pH12)-originating from the Bayer process in the production of alumina,which was probed in catalytic pyrolysis to determine its feasibility as a solid catalyst for bio-oil formulation.The red mud was characterized using X-ray fluorescence,XRD(X-ray diffraction),TG-DTG(thermogravimetry-derivative thermogravimetry),BET(surface area and pore size analyzer)measuring and testing techniques.Experiments of non-catalytic and catalytic pyrolysis of 40-60 mesh size corn stalk powder were channelled for bio-oil production in a fixed bed reactor.It was ascertained that adding different proportions of red mud had minute influence on bio-oil production rate and product distribution.The study signaled that liquid yield from the catalytic pyrolysis was lower than that from non-catalytic pyrolysis.Through a series of bio-oil characterization,it was encountered that the most obviously change in the bio-oil from catalytic pyrolysis was significant acidity reduction(pH4).Meanwhile,the content of ketones and phenols was enhanced.Hence,the co-processing of agricultural waste and by-products alumina industry may offer an economical and environmentally friendly way of catalytic pyrolysis with abbreviating the red mud environmental effects.