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Stereodefined tetraarylethylenes:Synthesis and applications

作     者:Minghao Zhang Wanxiang Zhao 

作者机构:State Key Laboratory of Chemo/Biosensing and ChemometricsCollege of Chemistry and Chemical EngineeringHunan UniversityChangshaP.R.China 

出 版 物:《Aggregate》 (聚集体(英文))

年 卷 期:2021年第2卷第4期

页      面:122-136页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:National Natural Science Foundation of China,Grant/Award Numbers:21971059,21702056 National Program forThousandYoungTalents of China Fundamental Research Funds 

主  题:aggregation-induced emission stereoselective synthesis tetraarylethylenes 

摘      要:Luminescent materials with efficient aggregate-state emissions are of growing interest due to their widespread applications in chemo-/biosensing and optoelectronic ***-induced emission(AIE)opens a new avenue for the applications of aggregate-state luminescent *** the AIE luminogens(AIEgens),tetraarylethylenes(TAEs)are typical AIEgens with a simple molecule scaffold and could be utilized as a framework for further elaboration,enabling structure-property-function relationship studies and multi-functional *** the existing approaches for the preparation of tetraarylethenes(TAEs)typically produce stereoisomeric mixtures,stereoselective synthesis of tetraarylethenes with desired geometry is a great *** this review,we systematically compile the synthetic methodologies for the construction of TAEs in excellent regio-and *** virtues and limitations of each methodology are discussed in detail as ***,the applications and the differences of properties between TAEs stereoisomers are introduced.

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