Electrochemical regioselective synthesis of N-substituted/unsubstituted 4-selanylisoquinolin-1(2H)-ones
Electrochemical regioselective synthesis of N-substituted/unsubstituted 4-selanylisoquinolin-1(2H)-ones作者机构:School of Chemistry and Chemical EngineeringUniversity of South ChinaHengyang 421001China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2022年第33卷第3期
页 面:1501-1504页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:financial support from Hunan Provincial Natural Science Foundation of China (Nos. 2019JJ50506 and2019JJ20008) Project supported by the Research Foundation of Education Bureau of Hunan Province (No. 19B501)
主 题:Organodiselenide Electrochemistry Radical Atom economy Additives-free
摘 要:A novel and efficient electro-chemical initiated radical strategy was developed for the preparation of both N-substituted and N-unsubstituted 4-selanylisoquinolin-1(2H)-ones through selenylation of isoquinolin-1(2H)-ones with organodiselenides under chemical oxidant-, additive-free and ambient conditions.