Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

作     者：Shigehiro Takahashi Naoyuki Abiko Nobuhiro Haraguchi Hiroyuki Fujita Eriko Seki Tetsuya Ono Kentaro Yoshida Jun-ichi Anzai 

作者机构：Graduate School of Pharmaceutical SciencesTohoku UniversityAramakiAoba-kuSendai 980-8578Japan School of Pharmaceutical SciencesOhu University31-1 MisumidoTomita-machiKoriyamaFukushima 963-8611Japan 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2011年第23卷第6期

页      面：1027-1032页

核心收录：

学科分类：082803[工学-农业生物环境与能源工程] 08[工学] 0828[工学-农业工程] 0804[工学-仪器科学与技术] 

基　　金：supported in part by a Grant-in-Aid (Asia-Africa Program) from Tohoku University 

主　　题：ferroceneboronic acid sugar phenolic compound cyclic voltammetry pollutants in water electrochemical determination 

摘      要：A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid（FBA） as a redox-active marker.A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0,respectively,while another pair of redox peaks was observed in the presence of diol or phenolic compounds *** results were rationalized based on the formation of boronate esters of FBA with the added *** changes in the redox peak currents were dependent on the concentration of the additives,suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.