Solvothermal Synthesis,Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ)Complex with 2-(4-Methylbenzoyl)benzoic Acid

作     者：LI Wei LI Chang-Hong LI Yu-Lin KUANG Yun-Fei 李薇;李昶红;李玉林;匡云飞

作者机构：School of Chemistry and Materials ScienceHengyang Normal UniversityHengyang 421008China School of Materials and Chemical EngineeringHunan Institute of TechnologyHengyang 421002China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2021年第40卷第7期

页      面：878-884,838页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Natural Science Foundation of Hunan Province(2019JJ60021) Industry and Research Key Project of Hengyang City(2019jhzx1093) 

主　　题：binuclear nickel(Ⅱ)complex spectrum analysis thermal stability magnetic property 

摘      要：A new binuclear nickel(Ⅱ)complex[Ni_(2)(MBBA)_(2)(HPT)_(2)(H_(2)O)_(2)]·2H_(2)O(1)was synthesized with nickel hydroxide,2-(4-methylbenzoyl)benzoic acid(HMBBA)and 3-(pyridin-2-yl)-1H-1,2,4-triazole(HPT).It crystallizes in the monoclinic space group P21/n with a=14.5902(13),b=8.8191(6),c=17.6120(14)Å,β=110.830(9)º,V=2118.0(3)Å^(3),M_(r)=958.26,D_(c)=1.503 g/cm^(3),Z=2,μ(MoKa)=0.959,F(000)=992,the final GOOF=1.001,R=0.0353 and wR=*** central Ni(Ⅱ)ion is coordinated by two oxygen and three nitrogen atoms,forming a distorted square pyramidal *** XRD,TG,spectrum analysis and magnetic properties of 1 were studied.