Progress and perspective of the cathode/electrolyte interface construction in all-solid-state lithium batteries

作     者：Shiming Su Jiabin Ma Liang Zhao Kui Lin Qidong Li Shasha Lv Feiyu Kang Yan-Bing He 

作者机构：Shenzhen Geim Graphene CenterInternational Graduate School at ShenzhenTsinghua UniversityShenzhenChina Laboratory of Advanced MaterialsSchool of Materials Science and EngineeringTsinghua UniversityBeijingChina Key Laboratory of Beam Technology of Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijingChina 

出 版 物：《Carbon Energy》 (碳能源（英文）)

年 卷 期：2021年第3卷第6期

页      面：866-894页

核心收录：

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0808[工学-电气工程] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：National Natural Science Foundation of China(U2001220) the Local Innovative Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01N111) the Shenzhen Technical Plan Project(Nos.JCYJ20180508152210821,JCYJ20170817161221958,and JCYJ20180508152135822) the Shenzhen All-Solid-State Lithium Battery Electrolyte Engineering Research Center(XMHT20200203006) 

主　　题：cathode configuration design interface lithium battery solid-state electrolyte 

摘      要：Security risks of flammability and explosion represent major problems with the use of conventional lithium rechargeable batteries using a liquid *** application of solid-state electrolytes could effectively help to avoid these safety ***,integrating the solid-state electrolytes into the all-solid-state lithium batteries is still a huge challenge mainly due to the high interfacial resistance present in the entire battery,especially at the interface between the cathode and the solid-state electrolyte pellet and the interfaces inside the ***,recent progress made from investigations of cathode/solid-state electrolyte interfacial behaviors including the contact problem,the interlayer diffusion issue,the space-charge layer effect,and electrochemical compatibility is presented according to the classification of oxide-,sulfide-,and polymer-based solid-state *** also propose strategies for the construction of ideal next-generation cathode/solid-state electrolyte interfaces with high room-temperature ionic conductivity,stable interfacial contact during long cycling,free formation of the space-charge region,and good compatibility with high-voltage cathodes.