Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries

作     者：Chiwei Xu Zhengwei Yang Xikun Zhang Maoting Xia Huihui Yan Jing Li Haoxiang Yu Liyuan Zhang Jie Shu Chiwei Xu;Zhengwei Yang;Xikun Zhang;Maoting Xia;Huihui Yan;Jing Li;Haoxiang Yu;Liyuan Zhang;Jie Shu

作者机构：School of Materials Science and Chemical EngineeringNingbo UniversityNingbo 315211ZhejiangPeople’s Republic of China 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2021年第13卷第11期

页      面：92-127页

核心收录：

学科分类：0808[工学-电气工程] 081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

基　　金：This work was sponsored by NSAF Joint Fund(U1830106) Science and Technology Innovation 2025 Major Program of Ningbo(2018B10061) K.C.Wong Magna Fund in Ningbo University 

主　　题：Prussian blue analogues Electrochemistry Cathode Aqueous batteries Desalination batteries 

摘      要：In the applications of large-scale energy storage,aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost ***,carrier ions always exhibit huge hydrated radius in aqueous electrolyte,which brings difficulty to find suitable host materials that can achieve highly reversible insertion and extraction of *** to open threedimensional rigid framework and facile synthesis,Prussian blue analogues(PBAs)receive the most extensive attention among various host candidates in aqueous ***,a comprehensive review on recent progresses of PBAs in aqueous batteries is *** on the application in different aqueous systems,the relationship between electrochemical behaviors(redox potential,capacity,cycling stability and rate performance)and structural characteristics(preparation method,structure type,particle size,morphology,crystallinity,defect,metal atom in highspin state and chemical composition)is analyzed and summarized *** can be concluded that the required type of PBAs is different for various carrier *** particular,the desalination batteries worked with the same mechanism as aqueous batteries are also discussed in detail to introduce the application of PBAs in aqueous systems *** report can help the readers to understand the relationship between physical/chemical characteristics and electrochemical properties for PBAs and find a way to fabricate high-performance PBAs in aqueous batteries and desalination batteries.