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Room Temperature Synthesis of Gold Nanokites in Polyvinyl Alcohol-Sodium Dodecyl Sulfate Aggregations Aqueous Solution

Room Temperature Synthesis of Gold Nanokites in Polyvinyl Alcohol-Sodium Dodecyl Sulfate Aggregations Aqueous Solution

作     者:Ren, Yueping Liu, Jia Feng, Feng Chen, Tingzhong Fang, Yun 

作者机构:School of Chemical & Material Engineering Jiangnan University Wuxi Jiangsu 214122 China 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:2011年第29卷第9期

页      面:1955-1960页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基  金:Project supported by the National Natural Science Foundation of China (No. 20871059) and Jiangsu Provincial Post Graduate Innovation Plan (No. CX08B_118Z) 

主  题:gold nanostructures nanokites polyvinyl alcohol sodium dodecyl sulfate 

摘      要:Controlled synthesis of asymmetrical gold nanokites was realized by reducing HAuCl4 with polyvinyl alcohol (PVA) in PVA-sodium dodecyl sulfate (SDS) aggregations aqueous solution at room temperature without any addi- tional reducing agents. The crystal structures, optical property and growth process of the gold nanokites were inves- tigated by X-ray diffraction (XRD), Vis-NIR spectrum and transmission electron microscope (TEM). HAuCl4 con- centration dramatically influenced the morphologies of the products. When HAuCl4 concentration was increased from 0.5 mmol·L^-1 to 2.2 mmol·L^-1, the products changed from network-like nanostructures to nanokites, nanoleaves and microplates. SDS was indispensable for the formation of gold nanokites and without SDS su- per-branched structures became the dominant products.

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