Synthesis of perylene-bridged bis(dibenzo-24-crown-8) and its assembly behavior with a fullerene-based secondary dibenzylammonium salt

作     者：YAO HaiQing,ZHANG HengYi,HAN Min,DING ZhiJun,ZHANG ZhiJun & LIU Yu State Key Laboratory of Elemento-Organic Chemistry Department of Chemistry,Nankai University,Tianjin 300071,China 

作者机构：State Key Laboratory of Elemento-Organic Chemistry Department of Chemistry Nankai University Tianjin China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2010年第53卷第9期

页      面：1982-1986页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Basic Research Program of China (973 Program) (2006CB932900) the National Natural Science Foundation of China (20932004 and 20772063) 

主　　题：crown ether perylene fullerene pseudorotaxane 

摘      要：This paper reports the synthesis of a perylene-bridged bis(crown ether) through the condensation reaction between primary amine-armed dibenzo-24-crown-8 and 3,4,9,10-perylenetetracarboxylic *** with a perylene moiety at the wheel and a fullerene unit in the middle of the axle was prepared,which was evidenced by 1H NMR and fluorescence *** investigations show that the formation and disassociation of the pseudorotaxane can be controlled by the alternating addition of KPF6 and 18-crown-6,following the change of the florescence intensity of perylene.