Production of biomass-derived monomers through catalytic conversion of furfural and hydroxymethylfurfural

作     者：hirong Yang Jing Zhang Gang Qian Xuezhi Duan Xinggui Zhou Zhirong Yang;Jing Zhang;Gang Qian;Xuezhi Duan;Xinggui Zhou

作者机构：State Key Laboratory of Chemical EngineeringEast China University of Science and TechnologyShanghai200237China 

出 版 物：《Green Chemical Engineering》 (绿色化学工程（英文）)

年 卷 期：2021年第2卷第2期

页      面：158-173页

核心收录：

学科分类：081702[工学-化学工艺] 080703[工学-动力机械及工程] 08[工学] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 

基　　金：supported by the National Natural Science Foundation of China(22008074,22008072,21991103) Natural Science Foundation of Shanghai(20ZR1415700) China Postdoctoral Science Foundation(2020M671025,2019TQ0093) 

主　　题：Biomass-derived monomers Catalyst design Furfural Hydroxymethylfurfural Heterogeneous catalysis 

摘      要：The synthesis of biomass-derived monomers has received great attention in recent years,motivated by the depletion of fossil fuels and environmental ***,the intrinsic functionality within the biomass or biomass-derived chemicals has great potential to produce new types of monomers containing multiple acid or alcohol groups,thereby leading to materials with novel *** their versatile functional groups and easy production from cellulose/hemicellulose,furfural and hydroxymethylfurfural were regarded as very important biomass-derived platform chemicals through which multiple monomers can be produced via heterogeneous *** the current review,recent development in heterogeneous catalysis for the production of 6 bio-based monomers,furfuryl alcohol,2,5-bis(hydroxymethyl)furan,2,5-bis-(hydroxymethyl)tetrahydrofuran,1,5-pentanediol,1,6-hexanediol,and 2,5-furandicarboxylic acid,from furfural and hydroxymethylfurfural is reviewed and *** major challenge is how to efficiently and selectively convert specific functional group(s)in furfural and hydroxymethylfurfural during the production of these ***,catalyst stability issues need to be addressed due to necessity of using hot water as reaction medium and high tendency of carbonaceous deposit formation on catalyst *** current review mainly focuses on efforts of catalytic site design and modification,including selection of metal/support,use of synergy between metal and support,tuning metal size,use of inverse catalysts,adding catalytic promoters,constructing bimetallic sites,etc.,to realize efficient,selective and stable production of bio-based monomers from furfural and hydroxymethylfurfural.