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DETERMINATION OF DEGREE OF CHARGE TRANSFER IN CONDUCTING LANGMUIR-BLODGETT FILM OF BEDT-TTF-TCNQ

DETERMINATION OF DEGREE OF CHARGE TRANSFER IN CONDUCTING LANGMUIR-BLODGETT FILM OF BEDT-TTF-TCNQ

作     者:Yu Fang XIAO Zhong Qi YAO Dao Sen JIN Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1993年第4卷第6期

页      面:555-558页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

主  题:TTF Figure Th DETERMINATION OF DEGREE OF CHARGE TRANSFER IN CONDUCTING LANGMUIR-BLODGETT FILM OF BEDT-TTF-TCNQ 

摘      要:A mixed Langmuir-Blodgett film was built up by mixture 1:1 of bis (ethyldithio)tetrathiafulvalene-tetracyanoquinodimethane/stearie acid(BEDT-TTF- TCNQ/SA).A degree of charge transfer(CT)in complex of BEDT-TTF with TCNQ was estimated at 0.477~0,486 by Raman frequencies of central Vc=c and Vc-s,The existence of charge transfer in BEDT-TTF-TCNQ has been confirmed by FTIR and XPS spectroscopy.

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