New Amines and Activation Modes in Asymmetric Aminocatalysis
作者机构:Key Laboratory of Drug-Targeting and Drug Delivery System of the Ministry of Education and Sichuan Research Center for Drug Precision Industrial TechnologyWest China School of PharmacySichuan UniversityChengdu 610041China College of PharmacyThird Military Medical UniversityShapingbaChongqing 400038China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2021年第39卷第7期
页 面:1775-1786页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:We are grateful for the financial support from the NSFC(21931006 and 21961132004) the Fundamental Research Funds for the Central Universities,and China Postdoctoral Science Foundation(2019M663488) Postdoctoral Foundation of Sichuan University(2020SCU12019)
主 题:Organocatalysis Aminocatalysis Amine/thiol double catalysis Cycloaddition Domino reactions
摘 要:Asymmetric aminocatalysis has become one of the most powerful strategies for the transformations of carbonyl substances over the past two ***,we describe the research from our laboratory that significantly expands the horizon of *** includes the development and application of cinchona-based primary amines,fruitful reactions based on HOMO-raising strategy,and the disclosure of amine/thiol double activation catalysis.