Catalytic oxidation of cyclohexene to cyclohexanone by a triple system in acidic aqueous acetonitrile medium

作     者：Li, HM Ye, XK Yang, XG Wu, Y 

作者机构：Chinese Acad Sci Changchun Inst Appl Chem Changchun 130022 Jilin Peoples R China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1997年第15卷第6期

页      面：512-527页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主　　题：cyclohexene oxidation cyclohexanone hydroquinone Pd(OAc)(2) iron phthalocyanine 

摘      要：The catalytic oxidation of cyclohexene to cyclohexanone using Pd(OAc)(2)/HQ/FePc was investigated in an acidic aqueous solution of acetonitrile. The role of each component of this system in the oxidation of cyclohexene was explored by means of UV-VIS, IR, XPS spectroscopy and. cyclic voltammetry, respectively. Based on the experimental results, the mechanism of the oxidation of cyclohexene catalyzed by Pd(OAc)(2)/HQ/FePc was elucidated.