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Physicochemical properties of coconut husk activated carbon modified by Fe(N0_(3))_(3)and Mn(N0_(3))_(2)

作     者:Hong-ming Long Bang-fu Huang Zhe Shi Lan-peng Liu De-fu Wang Lu Li Hong-ming Long;Bang-fu Huang;Zhe Shi;Lan-peng Liu;De-fu Wang;Lu Li

作者机构:Key Laboratory of Metallurgical Emission Reduction&Resources Recycling(Anhui University of Technology)Ministry of EducationMa'anshan 243002AnhuiChina Department of Metallurgical EngineeringKunming University of Science and TechnologyKunming 650093YunnanChina Clean Metallurgy Key Laboratory of Complex Iron ResourcesUniversity of Yunnan ProvinceKunming 650093YunnanChina 

出 版 物:《Journal of Iron and Steel Research International》 (J. Iron Steel Res. Int.)

年 卷 期:2021年第28卷第5期

页      面:530-537页

核心收录:

学科分类:081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基  金:The authors are grateful for Open Fund of Key Laboratory of Ministry of Education for metallurgical emission reduction and comprehensive utilization of resources(JKF19-08),General Project of Science and Technology Plan of Yunnan Science and Technology Department(2019FB077 and 202001AT070029) the Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(Grant No.FMRUlab-20-4) 

主  题:HNO_(3) Fe(N0_(3))_(3) Mn(N0_(3))_(2) Coconut husk activated carbon Physicochemical property Modification mechanism 

摘      要:Fe-loaded activated carbon(AC)has high surface acidity and more active sites,while manganese-loaded AC has high oxygen *** husk AC modified by Fe-Mn was studied with the aim of revealing the modification ***,HNO_(3)AC was prepared using the nitric acid immersion ***,Fe-Mn/AC was prepared using the Fe(N0_(3))_(3)and Mn(N0_(3))_(2)sequential *** effects of HNO_(3),Fe(N0_(3))_(3),and Mn(N0_(3))_(2)on the pore texture and surface chemical characteristics of carbon materials were examined by scanning electron microscopy,Brunauer-Emmett-Teller(BET)analysis,X-ray diffraction and Fourier-transform infrared *** surface topography,pore structure,active material,and functional groups of AC,HNO_(3)/AC,and Fe-Mn/AC were systematically *** following results were *** surface of HNO_(3)AC has more ditches and air voids;the micropores of HNO_(3)AC are deformed and flattened compared to those of *** surface of Fe-Mn/AC exhibits an accumulation ***_(2)O_(4)and FeMn_(2)O_(4)formed more pore *** and HNO_(3)AC have numerous *** higher loading quantity of Fe-Mn results in bigger specific *** active components of Fe-Mn/AC-1,Fe-Mn/AC-2,Fe-Mn/AC-3,and Fe-Mn/AC-4 are MnFe_(2)O_(4),MnO_(0.43)Fe_(2.57)O_(4),Mn_(3)O_(4),and ot-Fe_(2)O_(3)*** surface functional groups of AC and HNO_(3)AC are oxygen-containing functional *** effect of Fe-Mn modifying conditions on functional group species is rare;however,Fe/AC has more oxygen-containing functional *** research findings can aid in the desulfurization and denitrification of the Fe-Mn/AC catalyst.

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