Novel Zn(Ⅱ) ladder-like coordination polymer constructed from designed ferrocenyl ligand

作     者：Hai Fang Zhang Zi Feng Li Gang Li Li Peng Wang Jia Bin Li Guang Jian Mei 

作者机构：Department of Chemistry Zhengzhou University Zhengzhou 450052 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2008年第19卷第12期

页      面：1499-1503页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：support by the National Natural Science Foundation of China (No.20501017) the Key Project of Chinese Ministry of Education (No.207067) the Project Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Chinese Ministry of Education and the Student Innovation Experimental Item of Zhengzhou University 

主　　题：Zinc(Ⅱ) Structure Coordination polymer Designed ferrocenyl ligand Thermal and electrochemical properties 

摘      要：Reaction of Zn（NO3）2·6H2O with 3-（4-carboxylphenylamino）-l-ferrocenyl-2-butylen-l-one （HL） and 4,4′-bipyfidine （4,4′- bipy） in methanol solution resulted in a novel ladder-like coordination polymer {[Zn2L2（μ2-L）2（4,4′-bipy）2]·MeOH}n （1）. Its crystal structure, thermal and electrochemical properties are presented.