Titanium-rich TS-1 zeolite for highly efficient oxidative desulfurization

作     者：Risheng Bai Yue Song Ge Tian Fei Wang Avelino Corma Jihong Yu Risheng Bai;Yue Song;Ge Tian;Fei Wang;Avelino Corma;Jihong Yu

作者机构：State Key Laboratory of Inorganic Synthesis and Preparative ChemistryCollege of ChemistryJilin UniversityChangchun130012China Instituto de Tecnología QuímicaUniversitat Polit
ecnica de Val
encia-Consejo Superior de Investigaciones CientíficasValencia46022Spain State Key Laboratory of Superhard MaterialsJilin UniversityChangchun130012China International Center of Future ScienceJilin UniversityChangchun130012China 

出 版 物：《Green Energy & Environment》 (绿色能源与环境（英文版）)

年 卷 期：2023年第8卷第1期

页      面：163-172页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the National Natural Science Foundation of China, China (Grant 21920102005, 22288101, and 21835002) the 111 Project, China (B17020) the European Union through the European Research Council, European Union (grant ERC-AdG-2014-671093, SynCatMatch) the Spanish Government through “Severo Ochoa”, Spain (SEV2016-0683, MINECO) for supporting this work the financial support from China Scholarship Council, China 

主　　题：TS-1 Zeolite Ti-rich Heterogeneous catalysis Oxidative desulfurization 

摘      要：The exploration of highly efficient catalysts based on nano-sized Ti-rich titanosilicate zeolites with controllable active titanium species is of great importance in zeolite catalytic ***,we reported an efficient and facile synthesis of nano-sized Ti-rich TS-1(MFI)zeolites by replacing tetrabutyl orthotitanate(TBOT)with tetrabutyl orthotitanate tetramer(TBOT-tetramer)as the titanium *** introduced TBOT-tetramer slowed down the zeolite crystallization process,and accordingly balanced the rate of incorporating Ti and the crystal growth and inhibited the massive formation of anatase ***,the prepared Ti-rich TS-1 zeolite sample had a Si/Ti as low as 27.6 in contrast to conventional one with a molar ratio of *** TBOT-tetramer endowed the titanosilicate zeolites with enriched active titanium species and enlarged external surface *** also impeded the formation of anatase species,resulting in superior catalytic behavior toward the oxidative desulfurization of dibenzothiophene compared with the conventional TS-1 zeolite counterpart prepared with TBOT.