Comparative Study of the Adsorption Thermodynamic Parameters Estimated through Different Approaches

作     者：Manuela Gomes Cardoso Odivan Zanella Leandro Marques Paim Isabel Cristina Tessaro Liliana Amaral Feris 

作者机构：Department of Chemical Engineering Federal University of Rio Grande do Sul Porto Alegre 90040040 Brazil 

出 版 物：《Journal of Chemistry and Chemical Engineering》 (化学与化工（英文版）)

年 卷 期：2014年第8卷第8期

页      面：757-766页

学科分类：0820[工学-石油与天然气工程] 080701[工学-工程热物理] 08[工学] 0807[工学-动力工程及工程热物理] 082002[工学-油气田开发工程] 

主　　题：Adsorption thermodynamic zeolite ammonium. 

摘      要：The equilibrium constant （K0）, change in free energy （△G）, enthalpy （△H） and entropy （△S） of ammonium adsorption by a Cuban natural zeolite were estimated at the temperatures of 25, 35, 45 and 55℃ using extensively used approaches. Equilibrium data were obtained in the concentration range 50-1,200 mg·L-1 of ammonium and used in the estimation of thermodynamic parameters. Freundlich＇s isotherm model was found as with the best adjustment to equilibrium data at 25, 45 and 55℃, whereas, Redlich-Peterson＇s model had a better performance at 35 ℃. A discontinuous and unusual behavior was observed on adsorption capacity of the zeolite, with an increase from 25 ℃ to 35 ℃ followed by a decrease from 35℃ to 55 ℃. K0 values presented differences that reached up to 105 from one methodology to other. Depending on the method considered, AS results indicated both increase or decrease in system degree of disorder and △G indicated both physisorption or chemisorption process, proving the poor correlation between the estimation proceedings of such important data. The results from Gaines and Thomas method were recognized as the most correlated to calorimetric studies, as well as to equilibrium data and observations related to system entropy.