Review on the recent development of Li_(3)VO_(4)as anode materials for lithium-ion batteries
为锂离子电池作为阳极材料在 Li3VO4 的最近的发展考察作者机构:School of Chemistry and Chemical EngineeringHenan University of TechnologyZhengzhou 450001China School of Environmental EngineeringHenan University of TechnologyZhengzhou 450001China Key Laboratory of High Specific Energy Materials for Electrochemical Power Sources of Zhengzhou CityHenan University of TechnologyZhengzhou 450001China Institute of Flexible ElectronicsNorthwestern Polytechnical UniversityXi’an 710072China
出 版 物:《Journal of Materials Science & Technology》 (材料科学技术(英文版))
年 卷 期:2021年第89卷第30期
页 面:68-87页
核心收录:
学科分类:081702[工学-化学工艺] 0808[工学-电气工程] 08[工学] 0817[工学-化学工程与技术]
基 金:supported by the National Natural Science Foundation,China(Nos.21773057,52071132 and U1904216) the Zhongyuan Thousand People Plan-The Zhongyuan Youth Talent Support Program(in Science and Technology),China(No.ZYQR201810139) the Innovative Funds Plan of Henan University of Technology,China(No.2020ZKCJ04) Fundamental Research Funds for the Henan Provincial Colleges and Universities in Henan University of Technology,China(No.2018RCJH01)
主 题:Lithium-ion batteries Li_(3)VO_(4) Anode material Electrochemical performance
摘 要:Among the various anodes,Li_(3)VO_(4)is a potential intercalation kind anode used in lithium-ion batteries(LIBs)that exhibits safer discharge voltage and higher capacity than graphite,a lower voltage plateau than Li_(4)Ti_(5)O_(12),and smaller volume difference in the Li^(+)intercalation/deintercalation process than metals and ***,the comparatively low electronic conductivity,low initial coulombic efficiency(ICE)and serious capacity decay make the Li_(3)VO_(4)anode unviable when it comes to practical ***,this paper reviews the research progress of Li_(3)VO_(4)in recent years,mainly including the strategies of developing different synthesis methods to construct unique morphology,through coating,compositing or elemental doping to increase the ICE,electronic conductivity and the cycle ***,the application of Li_(3)VO_(4)anode materials in other energy storage systems is ***,the development prospect and challenge of Li_(3)VO_(4)anodes are discussed.