Recent progress in production and usage of hydrogen peroxide

作     者：Shunichi Fukuzumi Yong-Min Lee Wonwoo Nam Shunichi Fukuzumi;Yong-Min Lee;Wonwoo Nam

作者机构：Department of Chemistry and Nano ScienceEwha Womans UniversitySeoul 03760Korea Graduate School of Science and EngineeringMeijo UniversityNagoyaAichi 468-8502Japan Research Institute for Basic SciencesEwha Womans UniversitySeoul 03760Korea 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2021年第42卷第8期

页      面：1241-1252页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the JSPS KAKENHI(16H02268)from MEXT Japan and by the CRI(2012R1A3A2048842) Basic Science Research Program(NRF-2020R1I1A1A01074630)through NRF of Korea 

主　　题：Hydrogen peroxide production Water oxidation Dioxygen reduction Photocatalytic oxygenation Reaction kinetics and mechanism 

摘      要：Hydrogen peroxide has attracted increasing interest as an environmentally benign and green oxidant that can also be used as a solar fuel in fuel *** review focuses on recent progress in production of hydrogen peroxide by solar-light-driven oxidation of water by dioxygen and its usage as a green oxidant and *** photocatalytic production of hydrogen peroxide is made possible by combining the e^(-)and 4e-oxidation of water with the e^(-)reduction of dioxygen using solar *** catalytic control of the selectivity of the e^(-)vs.4e-oxidation of water is discussed together with the selectivity of the e^(-)vs.4e-reduction of *** combination of the photocatalytic e^(-)oxidation of water and the e^(-)reduction of dioxygen provides the best efficiency because both processes afford hydrogen *** solar-light-driven hydrogen peroxide production by oxidation of water and by reduction of dioxygen is combined with the catalytic oxidation of substrates with hydrogen peroxides,in which dioxygen is used as the greenest oxidant.