Pd-Catalyzed Ortho-Directed C-H Glycosylation of Arenes Using N-linked Bidentate Auxiliaries

作     者：Quanquan Wang Wanjun Zhu Qikai Sun Gang He Gong Chen Quanquan Wang;Wanjun Zhu;Qikai Sun;Gang He;Gong Chen

作者机构：State Key Laboratory and Institute of Elemento-Organic ChemistryCollege of ChemistryNankai UniversityTianjin 300071China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2021年第39卷第3期

页      面：571-576页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：G.C.thanks NSFC-91753124 NSFC-21672105 NSFC-21421062 and NSFC-21725204 for financial support of this work 

主　　题：Pd-Catalyzed C-H Bidentate auxiliaries Glycosyl chloride Glycosylation 

摘      要：Main observation and conclusion A set of Pd-catalyzed ortho-directed C-H glycosylation reactions with glycosyl chloride donors using various N-linked bidentate auxil-iaries has been developed for synthesis of C-aryglycosides.A broad range of pyranose and furanose moieties can be installed on the ortho position of arylamine,carbazole,indole and benzylamine type substrates in high yield and with high regio-and *** auxiliaries can be readily installed and removed under relatively mild conditions.