Fabrication of Graphitic Carbon Nitride-Based Film:An Emerged Highly Efficient Catalyst for Direct C-H Arylation under Solar Light

作     者：Surabhi Chaubey Rajesh K.Yadav Tae Wu Kim Tara Chand Yadav Abhishek Kumar D.K.Dwivedi B.K.Pandey Atul P.Singh Surabhi Chaubey;Rajesh K.Yadav;Tae Wu Kim;Tara Chand Yadav;Abhishek Kumar;D.K.Dwivedi;B.K.Pandey;Atul P.Singh

作者机构：Department of Chemistry and Environmental ScienceMadan Mohan Malaviya University of TechnologyGorakhpur-273010U.PIndia Center for Nanomaterials and Chemical ReactionsInstitute for Basic Science(IBS)Daejeon 34141Republic of Korea Department of ChemistryKorea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea Department of BiotechnologyIndian Institute of Technology Roorkee-247667India Department of ChemistryInstitute of ScienceBanaras Hindu UniversityIndia Department of Physics and Material ScienceMadan Mohan Malaviya University of TechnologyGorakhpur 273010U.PIndia Department of ChemistryChandigarh UniversityMohaliIndia 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2021年第39卷第3期

页      面：633-639页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was supported by Madan Mohan Malaviya University of Technology (MMMUT) Gorakhpur U.P. India 

主　　题：Photocatalysis g-C_(3)N_(4)-FITC film photocatalyst C-H activation Heteroarenes Cyclic voltammetry 

摘      要：Main observation and conclusion Photoredox C-H bond formation can proceed in aerobic environment under solar light and has therefore become ***-days,different types of expensive novel metal complexes and nanomaterials have been urbanized as photocatalysts for direct C-H bond formation in between derivatives of heteroarenes(HAs)and aryl diazonium *** photocatalysts,however,still suffer from poor stability,high cost,and ***,a graphitic carbon nitride-based fluorescein isothiocyanate(g-C_(3)N_(4)-FITC)film pho-tocatalyst has been reported,which shows ecellent light harvesting ability,and band gap suitability to catalyze the metal free direct C-H arylation of HAs under solar light at ambient ***,the g-C_(3)N_(4)-FITC film photocatalyst can be reused four times without significant loss of activity,confirming the excellent photocatalytic *** current strategy to constructa g-C_(3)N_(4)-FITC film photocatalyst for direct C-H arylation opens a new path towards replacing metal-based catalysts in fine chemical Sy nthesis.