Synthesis and Crystal Structure of 3,5-Diphenyl-1,2-di(4-chlorophenyl)pyrrole

作     者：SHI Da-Qing SHI Chun-Ling ZHUANG Qi-Ya 

作者机构：Department of Chemistry Xuzhou Normal University Xuzhou Jiangsu 221116 China Key Laboratory of Biotechnology on MedicalPlants of Jiangsu Province Xuzhou 221116 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2005年第24卷第11期

页      面：1314-1317页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：This work was supported by the Natural Science Foundation of Jiangsu Education Department (No. 03KJB 150136) 

主　　题：pyrrole low-valent titanium reagent crystal structure 

摘      要：The title compound （C28H19Cl2N） has been synthesized by the reaction of dibenzoylmethane and N-（4-chlorobenzylidene）-4-chlorobenzenamine promoted by low-valent titanium reagent, and characterized by elemental analysis, IR, ^1H NMR and X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P2 1/C with a = 9.952（2）, b = 9.863（2）, c = 23.460（6） A, β = 99.62（2）°, V = 2270.4（9） A^3, Mr = 440.34, Z = 4, Dc = 1.288 g/cm^3, μ（MoKa） = 0.301 mm^-1, F（000） = 912, the final R = 0.0387 and wR = 0.0793. X-ray analysis reveals that the four phenyl rings in the pyrrole ring are not coplanar.