LOW-VALENT TITANIUM INDUCED REDUCTIVE COUPLING REACTION OF AROMATIC α-HYDROXY KETONES

作     者：Zi Jie HOU Li dun LIU~(**) Yu Lin LI State Key Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry of Lanzhou Univercity, Lanzhou 730000 Ningxia Medical College, Yinchuan 750004 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1992年第3卷第4期

页      面：279-280页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Supported by the National Science Foundation of China Supported by the National Education Commission Foundation of China 

主　　题：ppm HYDROXY KETONES LOW-VALENT TITANIUM INDUCED REDUCTIVE COUPLING REACTION OF AROMATIC 

摘      要：Treatment of aromatic α-hydroxy ketones with an activated Ti(O) reagent, prepared by reduction of TiCl_3 with a Zn-Cu couple, effects an intermolecular coupling reaction leading to the (Z)-1, 2, 3, 4-tetrarvl-2-butene and (E, E)-1, 2, 3, 4,-tetraryl-1, 3-butadiene. A possible reaction mechanism was proposed.