Investigation of charge interaction between fullerene derivatives and single-walled carbon nanotubes

作     者：Clément Delacou Il Jeon Keigo Otsuka Taiki Inoue Anton Anisimov Takenori Fujii Esko I.Kauppinen Shigeo Maruyama Yutaka Matsuo 

作者机构：Department of Mechanical EngineeringThe University of TokyoTokyoJapan KU-KIST Green School Graduate School of Energy and EnvironmentKorea UniversitySeoulSouth Korea Nanoscale Quantum Photonics LaboratoryRIKENSaitamaJapan Canatu LtdHelsinkiFinland Cryogenic Research CenterThe University of TokyoTokyoJapan Department of Applied PhysicsAalto University School of ScienceAaltoFinland Energy NanoEngineering LaboratoryNational Institute of Advanced Industrial Science and Technology(AIST)TsukubaJapan Institutes of Innovation for Future SocietyNagoya UniversityNagoyaJapan 

出 版 物：《InfoMat》 (信息材料（英文）)

年 卷 期：2019年第1卷第4期

页      面：559-570页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Japan Science and Technology Agency,Grant/Award Number:CIAiS Japan Society for the Promotion of Science,Grant/Award Numbers:JP15H05760,JP16H02285,JP17K04970,JP 18H05329,JP19K15669 Yashima Foundation 

主　　题：doping field-effect transistors fullerene single-walled carbon nanotubes thin films 

摘      要：The charge interaction and corresponding doping effect between single-walled carbonnanotubes (SWNTs) and various fullerene derivatives, namely, C60, phenyl-C61-butyricacid methyl ester (PC61BM), methano-indenefullerene (MIF), 10,100,40,400-tetrahydrodi[1,4]methanonaphthaleno[5,6]fullerene (ICBA), 1,4-bis(dimethylphenylsilylmethyl)[60]fullerene (SIMEF-1), and dimethyl(orthoanisyl) silylmethyl(dimethylphenylsilylmethyl)[60]fullerene (SIMEF-2), are investigated. A variety of analytical techniques,including field-effect transistors (FETs) made of horizontally aligned arrays ofSWNTs, is used as a means of investigation. Data from different measurements haveto be used to obtain a concrete evaluation for the fullerene-applied SWNTs. The datacollectively points toward the conclusion that fullerenes with high molecular orbitalenergy levels, namely, MIF, SIMEF-1, SIMEF-2, and PC61BM, induce p-type doping,while fullerenes with low molecular orbital energy levels, namely, ICBA and C60,induce n-type doping on the carbon nanotubes. Nevertheless, the SWNTs retained ptypecharacteristics because n-doping induced by the fullerenes are weak compared tothe p-doping of the water and oxygen on carbon nanotubes. This means that fullerenederivatives have the ability to fine-tune the energy levels of carbon nanotubes, whichcan play a crucial role in carbon nanotube-based electronics, such as solar cells, lightemittingdevices, and FETs.