High Quality Bio-Oil Obtained from Catalyzed Pyrolysis of Olive Mill Solid Wastes in a Bi-Functional Reactor
作者机构：MCEMA and LEADDER Laboratories Faculty of Sciences and EDST Lebanese University Hariri Campus Beirut Lebanon DICAAR—Dipartimento di Ingegneria Civile Ambientale e Architecttura Università de Cagliari Cagliari Italy Université de Haute Alsace Université de Strasbourg Axe Matériaux à Porosité Contr?lée (MPC) Institut de Science des Matériaux de Mulhouse (IS2M) Mulhouse Cedex France Invited Researcher at SATIE-IFSTTAR Université Gustave Eiffel Campus de Marne-La-Vallée Versailles France
出 版 物：《Materials Sciences and Applications》 (材料科学与应用期刊（英文）)
年 卷 期：2021年第12卷第1期
页 面：52-77页
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
主 题：Energy Conversion Bio-Oil Biomass Pyrolysis Reactor Olive Mill Solid Wastes SBA-15 Mesoporous Silica
摘 要：Olive Mill Solid Wastes (OMSW) released in nature without any treatment is a major environmental problem in the Mediterranean region. In this work, the catalyzed pyrolysis of OMSW has been investigated. A catalyst based on SBA-15 mesoporous silica doped with chromium ferrite nanoparticles was prepared by the double solvent technique (DS). The prepared catalyst was characterized by scanning electron microscopy (SEM), Wide and Small Angle X-ray Scattering (WAXS, SAXS), Energy Dispersive X-ray (EDX) and FT-IR spectroscopies. Reverse spinel chromium ferrite nanoparticles were located inside the SBA-15 pores as confirmed by SEM images. The obtained catalyst was tested for pyrolysis reactions of OMSW. Several parameters were studied to optimize the conditions of the pyrolysis reaction in order to increase the bio-oil conversion yield. The GC-MS results demonstrated that the quality of the obtained bio-oil was improved by decreasing the quantity of phenolic and oxygenated components as well as the size of the obtained molecules. The produced bio-oil from pyrolysis of OMSW is identical to that obtained from the pyrolysis of commercial cellulose under the same conditions. A 37% conversion yield of bio-oil was obtained for the best conditions.
维普期刊数据库