Low‐temperature synthesis of graphitic carbon‐coated silicon anode materials
作者机构:Department of Chemical and Environmental EngineeringUniversity of California‐RiversideRiversideCalifornia College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouChina
出 版 物:《Carbon Energy》 (碳能源(英文))
年 卷 期:2019年第1卷第2期
页 面:246-252页
核心收录:
学科分类:0830[工学-环境科学与工程(可授工学、理学、农学学位)] 0808[工学-电气工程] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
基 金:Power Energy Solutions Inc.
主 题:glucose graphitic carbon Li‐ion batteries silicon anode
摘 要:We report the synthesis of a high‐performance graphitic carbon‐coated silicon(Si@GC)composite material for lithium‐ion batteries via a scalable production route.Porous Si is produced from the magnesiothermic reduction of commercial silica(SiO2)precursor followed by low‐temperature graphitic carbon coating using glucose as the precursor.The obtained Si@GC composite achieves an excellent reversible specific capacity of 1195 mAh g−1 and outstanding cycle stability.The thick Si@GC anode(3.4 mg cm^−2)in full cells with commercial lithium iron phosphate cathode delivers a remarkable performance of 800 mAh g^−1 specific capacity and 2.7 mAh cm^−2 areal capacity as well as 93.6%capacity retention after 200 cycles.