A Novel Tripyridyldiamine Nickel Complex:Synthesis, Structure and Characterization

作     者：LI Yan WANG Wen-Zhen TANG Chang-Sheng JIA Xin-Gang FAN Wei WANG Li 李彦;王文珍;汤昌盛;贾新刚;樊维;汪力

作者机构：School of Chemistry and Chemical EngineeringXi’an Shiyou UniversityXi’an 710065China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2021年第40卷第1期

页      面：91-95,4页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(No.11847140) the Natural Science Foundation of Shannxi Province(No.2019JZ-44 2017JQ2009) the Natural Science Basic Research Plan in Shaanxi Province of China(No.2019JQ-490) the Scientific Research Program Funds by Shannxi Provincial Education Department(No.Z18165) the Xi’an Shiyou University Postgraduate Innovation and Practical Ability Training Project(No.YCS17211017) 

主　　题：tripyridyldiamine functional complexes supramolecular chemistry crystal structures 

摘      要：A novel nickel(II)complex[Ni(H2 tpda)(NCS)2(CH3 OH)]was synthesized by using tripyridyldiamine as ligand and Ni(NCS)2 as starting materials,and characterized by a variety of techniques including single-crystal X-ray diffraction,IR spectroscopy and *** single-crystal structure reveals that the complex exhibits as a neutral molecule and that the central atom Ni(II)is octahedrally coordinated by an H2 tpda,two NCS-ions and a ligand molecule CH3 *** 3 D supramolecular network is formed through hydrogen bonds andπ-π*** complex can catalyze the addition reaction of carbon dioxide and propylene oxide.