Insight into solute-solute and solute-solvent interactions of semicarbazide hydrochloride in water and D-glucose/D-sucrose+water solutions at temperatures(293.15 to 318.15)K

作     者：Ankita Dinesh Chand Anil Kumar Nain Ankita;Dinesh Chand;Anil Kumar Nain

作者机构：Department of ChemistryDyal Singh CollegeUniversity of DelhiNew Delhi 110003India Department of ChemistryUniversity of DelhiDelhi 110007India Department of ChemistryAmity University Dubai CampusDubai International Academic CityDubaiUAE 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2020年第28卷第12期

页      面：3086-3095页

核心收录：

学科分类：0710[理学-生物学] 1007[医学-药学(可授医学、理学学位)] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0817[工学-化学工程与技术] 0703[理学-化学] 10[医学] 

基　　金：The authors are thankful to the Head  Department of Chemistry (University of Delhi)  Delhi  India for encouragement and providing facilities 

主　　题：Density Ultrasonic speed Viscosity Semicarbazide hydrochloride Carbohydrates Solute-solvent interactions 

摘      要：The solute-solute and solute-solvent interactions of drug semicarbazide hydrochloride with carbohydrates(Dglucose/D-sucrose)are investigated by using volumetric,viscometric and acoustic *** measurements of the densitiesρ,ultrasonic speeds u,and viscositiesη.of semicarbazide hydrochloride in 5% and 10%D-glucose/D-sucrose+water(w/w)solutions were carried out at temperatures(293.15-318.15)K and at pressure,p=101 *** apparent molar volumes,Vϕ,limiting apparent molar volumes,V°ϕ,apparent molar compressibilities,Ks,ϕ,limiting apparent molar compressibilities,K°s;ϕ,partial molar expansibilities,E°ϕ,transfer volumes,V°ϕ;tr and transfer compressibilities,K°s;ϕ;tr have been calculated from the experimental *** viscosity data were examined by using the Jones-Dole equation and the viscosity A and B coefficients were *** results are discussed in terms of solute-solute and solute-solvent interactions in these *** structure making/breaking ability of semicarbazide hydrochloride is examined using the sign of temperature derivative of Bcoefficient,dB/dT.