A FACILE SYNTHESIS OF HYPERBRANCHED POLYIMIDES FROM 2,6,12-TRIAMINOTRIPTYCENE

作     者：程琳 

作者机构：Department of Materials Science & EngineeringHuaqiao University 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2010年第28卷第1期

页      面：69-76页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.50673031 and 50973036) the Natural Science Foundation of Fujian Province(No.2008F3067) 

主　　题：Triptycene Hyperbranched polymer Polyimides. 

摘      要：Based on monomer 2,6,12-triaminotriptycene, hyperbranched polyimides with high molecular weight modified with different terminal functional groups were obtained by polymerization of A2 ＋ B3 system. The prepared hyperbranched polyimides had good solubility in CHCl3, DMF and THF, and performed no detective Tgs in the range of 50-330℃ and high TdS （5%） above 455℃.