Hydrolytic　dynamics　of　pesticide　N＇－（2，4－dimethylphenyl）－N－methylformamidine　in　aquatic　solution

作     者：Mo Hanhong Yang Kewu An Fengchun Liu Ye (Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China) 

作者机构：Res. Ctr. for Eco-Environ. Sciences Chinese Academy of Sciences Beijing 100085 China 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：1996年第8卷第2期

页      面：185-190页

核心收录：

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 082803[工学-农业生物环境与能源工程] 08[工学] 0828[工学-农业工程] 

主　　题：pesticide N'- ( 2,4-dimethylphenyl)-N-methylformamidine hydrolysis degradation. 

摘      要：The hydrolytic dynamics of pesticide N -(2,4-dimethylphenyl)-N-methylformamidine (DMA) in aquatic solution and its degradation in simulated aquatic ecosystem were investigated. The results showed that the compound was not very stable in aqueous solution and easily decomposed in alkaline solution. It was stable below pH5 and there was obvious tendency that the compound was easily decomposed when PH was greater than 6. The reaction rate constant of DMA increased with increasing of either pH value Or temperature of reaction medium. The half-life values of hydrolysis for DMA at 25℃ were 15. 92 days at pH 6, and 1. 40 days at pH 9 , respectively. The temperature coefficient and activation energy of hydrolysis for DMA was 2. 9 and 78. 74kJ. mol-1 , respectively. The degradation of DMA in simulated aquatic ecosystem was similar to that in buffer solution in the laboratory. The half-life values of degradation for DMA at 26℃ in simulated aquatic ecosystem were 3. 23 days at pH 9. 13 and 1. 41 days at pH 8. 28 , respectively.